PtRu nanoparticles supported on noble carbons for ethanol electrooxidation
نویسندگان
چکیده
In this work, three cytosine derived nitrogen doped carbonaceous materials (noble carbons, NCs) with different atomic C/N ratios and porous networks have been synthesized used as supports for PtRu electrocatalysts in the ethanol oxidation reaction (EOR) clean hydrogen production. Both, metal phase carbon support play critical roles final performance. Lower NPs size distribution was obtained over low (i.e., 4 6) defined porosity 1701 m2 g?1 PtRu/CNZ 1834 PtRu/CLZ, respectively). contrast, a lower ratio poor network 65 g?1, PtRu/CLK) led to largest particle fostered an increase of alloying degree between Pt Ru 3% ~ 6 28% 3). Electrochemical active surface area found decreasing alloy extent, due higher availability sites. Accelerated degradation tests showed that PtRu/NCs outperform similar on commercial pointing at stabilizing effect NCs. exhibited best electrochemical performance 69.1 mA mgPt?1), outperforming PtRu/CLZ PtRu/CLK by 3- 9-fold, respectively, suitable compromise sizes, alloy, textural properties elemental composition. Best anodes were scaled-up proton exchange membrane cell proved provide electrocatalytic activity (262 cm?2 energy requirements), matching values state art EOR electrocatalysts.
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ژورنال
عنوان ژورنال: Journal of Energy Chemistry
سال: 2022
ISSN: ['2096-885X', '2095-4956']
DOI: https://doi.org/10.1016/j.jechem.2021.07.004